The free quon gas suffers Gibbs' paradox.
نویسنده
چکیده
where f, g are test functions, i.e., elements of the oneparticle space with inner product 〈f, g〉, a(f) is a Hilbert space operator with adjoint a†(f) depending linearly on f . The deformation parameter q must be real, and we take it in the interval −1 < q < 1. At the endpoints of this interval the relations become the canonical commutation relations (q = 1), and the canonical anticommutation relations (q = −1), respectively. The Quons with q = 0 were the first example of this type considered by Greenberg [1]. The relations (1) with q = 0 also play a central rôle in the theory of freely independent random variables [4–6] initiated by Voiculescu [7]. Such systems have been used as a driving noise [5] in quantum stochastic differential equations [8]. The extension of this work to other values of q has led to an independent proposal of the relations (1) [9]. The relations also arise as the commutation relations of collective degrees of freedom in a system of many components obeying anomalous statistics [10].
منابع مشابه
Multi-Component-Multiphase Flash Calculations for Systems Containing Gas Hydrates by Direct Minimization of Gibbs Free Energy
The Michelsen stability and multiphase flash calculation by direct minimization of Gibbs free energy of the system at constant temperature and pressure, was used for systems containing gas hydrates. The solid hydrate phase was treated as a solid solution. The fugacities of all components of the hydrate phase were calculated as a function of compositions by the rearranged model of van der Wa...
متن کاملThermal Radiation Effect in the Free Expansion of an Ideal Gas and Gibbs’ Paradox in Classical Thermodynamics
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in this universe, and hence also the particles of a gas, absorbs and radiates thermal energy. The interaction with the thermal radiation that is contained withi...
متن کاملInteraction with thermal radiation in the free expansion and mixing of ideal gases and Gibbs’ paradox in classical thermodynamics
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in this universe, and hence also the particles of a gas, absorbs and radiates thermal energy. The interaction with the thermal radiation that is contained withi...
متن کاملTheoretical thermodynamic study of Pyrazole in the gas phase at the different temperatures
The thermodynamic functions such as enthalpy (H), Gibbs free energy (G) and entropy (S) ofPyrazole was theoretically studied at 5 different temperatures 25, 30, 35, 40 and 45°C by usingGussian o3, software. First, the structural optimization of isolated Pyrazole was done in the gas phaseby appling the Density Functional Theory (B3LYP) level with 3-21G, 6-31G and 6-31+G(d) basissets. Moreover, v...
متن کاملGibbs paradox of entropy of mixing: experimental facts, its rejection and the theoretical consequences
Gibbs paradox statement of entropy of mixing has been regarded as the theoretical foundation of statistical mechanics, quantum theory and biophysics. A large number of relevant chemical and physical observations show that the Gibbs paradox statement is false. We also disprove the Gibbs paradox statement through consideration of symmetry, similarity, entropy additivity and the defined property o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review. D, Particles and fields
دوره 48 6 شماره
صفحات -
تاریخ انتشار 1993